高速逆流色谱法分离镧系和锕系元素的研究进展
Review of High-Speed Countercurrent Chromatography in Separation of Lanthanides and Actinides
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摘要: 在放射化学领域，镧系和锕系元素分离一直是研究热点之一。为实现燃耗分析，需要对溶解液中的镧系和锕系元素进行多组分的系统分离。常用的高压液相色谱法等由于处理量较小，无法满足分离要求。而液液萃取法具有较高的处理量，分离效率却较低。高速逆流色谱法(HSCCC)是一种新型的不需要固体载体的分离方法，它结合了液液萃取和分配色谱两者优点，已被广泛应用于生物活性物质的分离。其独特的优点在放化领域也引起了研究者们的注意。为此，本文介绍了高速逆流色谱的基本结构与原理特点，并就高速逆流色谱在镧系和锕系元素分离中的研究进展进行了综述，展望其在放化领域的应用前景。Abstract: In the field of radiochemistry, separation of lanthanides and actinides has always been one of the research hotspots. In order to achieve the burnup analysis, the lanthanide and actinide elements in the solution need to be separated. High pressure liquid chromatography and other commonly used methods cannot meet the separation requirements due to small processing capacity. On the other hand, liquid-liquid extraction method has a higher handling capacity, but the separation efficiency is low. High-speed countercurrent chromatography(HSCCC) is a novel separation method that gets rid of solid support. Having been widely used in the separation of bioactive substances, it combines the advantages of liquid-liquid extraction and distribution chromatography. Its unique advantages have also attracted the attention of radiochemistry researchers. In this paper, the basic structure, principle and characteristics of high-speed countercurrent chromatography(HSCCC) are introduced, the research progress in the separation of lanthanide and actinide elements is reviewed, and its application in radiochemistry is prospected.
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