熔融盐结构的研究进展

    Research Progress in Structure of Molten Salts

    • 摘要: 熔融盐结构的研究对其在熔融盐核发电站、乏燃料后处理、光热发电站等方面的应用有促进作用。本文总结了熔融盐短程结构与中程结构的研究进展,介绍了该研究常用的研究方法,讨论了熔融盐中阳离子的主要存在形式、平均配位数、配位数分布、离子之间的距离分布、阴阳离子交替、部分熔融盐中存在的共享阴离子的网络结构、X射线散射/中子散射实验所得的结构函数中每个峰的起源,并展望了该研究领域的进一步发展方向。

       

      Abstract: Investigation of molten salts structure will benefit its’ application in molten salts reactor, spent fuel reprocessing and concentrating solar power plant. This manuscript summarized previous researches concerning the short-range and intermediate-range structure of molten salts. The major existence form of cations, the average coordination number, distribution of coordination number, the distribution of ion distance, the cation-anion alternation, the anion-sharing network in molten salts are discussed in this article. It also addresses the origin of peaks in structure function that are obtained from X-ray scattering and neutron scattering experiments. Finally, this paper discusses the feature works that can be done in this research field. 

       

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