水体中铀的光催化剂研究进展

    Research Progress of Materials for Photocatalytic Reduction of Uranium in Water

    • 摘要: 近年来,半导体光催化方法在水体还原提铀方面取得了较大进展。光催化由于有着污染性较小、使用能源少、材料再利用率高等优点,已成为近年研究水体还原提铀的一个重要方向,并且也有核废水处理、海水提铀的潜力。本文综述了光催化还原铀的机理及其催化剂材料的特性、合成和分类方法,为了使分类更加直观具体,依据材料的主要组成元素或成分而不是结构进行分类,将其分为二氧化钛及其改性复合材料、石墨相氮化碳及其衍生物、铋系光催化剂、半导体金属硫化物光催化剂等。同时,分析了不同光催化剂的优缺点并进行了一系列的对比,为光催化还原提铀研究提供参考和依据。

       

      Abstract: In recent years, semiconductor photocatalytic methods have made great progress in the reduction and extraction of uranium from water. In recent years, due to its advantages of less pollution, low energy, and high material reuse efficiency, photocatalysis has become an important direction in the study of reduction and extraction of uranium in water, and it also has the potential to treat nuclear wastewater and extract uranium from seawater. This article reviews the mechanism of photocatalytic reduction of uranium, and the characteristics, synthesis and classification methods of catalyst materials. In order to make the classification more intuitive and specific, classification is based on composition rather than structure, and it is divided into titanium dioxide and its modified composite materials, graphite phase carbon nitride and its derivatives, bismuth photocatalysts, metal sulfide photocatalysts, etc. The advantages and disadvantages of different photocatalysts were analyzed and a series of comparisons were made to provide reference and basis for research on uranium extraction through photocatalytic reduction.

       

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