有机吸附材料处理放射性废水中铀的研究进展

    Research Progress on Organic Adsorbent Materials for Treatment of Uranium in Radioactive Wastewater

    • 摘要: 核能工业的快速发展产生了大量含铀放射性废水,其安全处理是环境保护与资源回收面临的关键挑战。吸附法因操作简单、成本低、适用性广,成为富集和去除放射性废水中铀的常用技术。随着材料科学的进步,各类有机吸附材料的研究与应用取得了显著进展。本文系统综述了用于铀吸附的有机材料,主要包括天然有机高分子(如纤维素、壳聚糖、海藻酸盐)、生物质废弃物(如农作物残渣、树叶)、微生物(如细菌、真菌、藻类)以及合成高分子材料(如离子印迹聚合物、有机骨架材料)。铀在溶液中主要以\mathrmUO_2^2+ 形态存在,其吸附机理主要涉及离子交换与表面配位。通过对材料进行离子印迹、交联、接枝、复合等改性处理,可有效引入含氧、含氮等官能团,从而大幅提升其对铀的吸附容量与选择性。例如,改性壳聚糖对铀的最大吸附容量可达619 mg/g,而某些磷酸盐基有机骨架材料在强酸条件下仍保持优异吸附性能。多数吸附过程符合准二级动力学和Langmuir等温吸附模型。未来研究应致力于开发在高盐、强酸或复杂离子干扰环境下仍具高选择性与稳定性的吸附剂,并结合X射线光电子能谱(XPS)、扩展X射线吸收精细结构(EXAFS)等先进表征技术深入揭示吸附机理。同时,需关注材料的循环再生性能、工程化应用潜力及环境友好性,以推动铀吸附材料从实验室研究走向实际应用。

       

      Abstract: The rapid development of the nuclear energy industry has resulted in the generation of large quantities of uranium-containing radioactive wastewater. The safe and efficient treatment of such wastewater constitutes a critical challenge for environmental protection and the recovery of valuable resources. Adsorption has become a commonly used technique for the enrichment and removal of uranium from wastewater due to its operational simplicity, low cost, and wide applicability. With continuous advancements in materials science, significant progress has been made in the research and practical application of various organic adsorbents. This paper systematically reviews the different types of organic materials employed for uranium adsorption, which primarily include natural organic polymers(such as cellulose, chitosan, and alginate), biomass wastes (for example, agricultural residues and leaves), microorganisms(including bacteria, fungi, and algae), as well as synthetic polymeric materials (notably ion-imprinted polymers and organic framework materials). In aqueous solutions, uranium predominantly exists in the form of the uranyl ion (\mathrmUO_2^2+ ). The principal adsorption mechanisms involve ion exchange and surface complexation between the uranyl ions and the functional groups present on the adsorbent materials. To significantly enhance adsorption performance, various modification methods-such as ion imprinting, cross-linking, grafting, and compositing-are applied. These techniques effectively introduce or enrich oxygen- and nitrogen-containing functional groups(e.g., –OH, –COOH, –NH2) on the material surfaces, thereby markedly improving both the adsorption capacity and selectivity for uranium. For instance, modified chitosan-based adsorbents can achieve a maximum uranium adsorption capacity of 619 mg/g. Furthermore, certain phosphate-based organic framework materials maintain excellent adsorption performance even under strongly acidic conditions. The adsorption processes for most of these materials conform to pseudo-second-order kinetics and can be well described by the Langmuir isotherm model. Future research should focus on the development of novel adsorbents that exhibit high selectivity and robust stability in challenging environments, such as those with high salinity, strong acidity, or complex mixtures of competing ions. It is essential to employ advanced characterization techniques—including X-ray photoelectron spectroscopy(XPS) and extended X-ray absorption fine structure(EXAFS) analysis—to gain deeper insights into the molecular-level adsorption mechanisms. Concurrently, greater attention must be paid to the cyclic regeneration capability, potential for engineering-scale application, and overall environmental friendliness of these adsorbent materials. Addressing these aspects is crucial for facilitating the transition of uranium adsorption technologies from laboratory-scale research to full-scale practical implementation.

       

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