双取代基冠醚钍固体配合物的制备及性质

摘要: 在四氢呋喃（ＴＨＮ）介质中合成了水合硝酸钍与４′，５′－二溴苯并－１５－冠－５及４′－溴－５′－硝基苯并－１５－冠－５的新固体配合物，并进行了元素分析、红外光谱、差热。热重和Ｘ－射线粉末衍射分析等性质表征。且通过ＫＢｒ压片和石蜡油糊法制样的对比研究，考察了用不同方法制样对配合物的红外光谱所产生的影响。

Abstract: PREPARATION AND CHARACTERIZATION OF THECOMPLEZES OF THORIUM AND BISPLACED CROWN ETHERSDONG WENKUI（Department of Environmental Engineering，Lanzhou Radway Institute，Lanzhou 730070）ABSTRACT The new solid complexes of hydrated thorium nitrate with 4′，5′-dibromobenzo- 1 5-crown-5and 4′- bromo-5′- nitrobenzo-1 5-crown-5 are prepared in tetrahydrofuran medium，and character-ized by the element analysis，IR spectrum，TG－DTA，X-ray powder diffraction analvsis.Theeffects of KBr-pressed-disk and Nujol Mull technique on the infrared spectra of the complexes arediscussed.Key words Thorium Crown ether Complex