粒度不均一交换剂的离子交换反应动力学——Ⅲ.异相同位素交换反应速度方程的应用
KINETICS OF ION EXCHANGE IN POLYDISPERSE SYSTEMS Ⅲ. APPLICATION OF RATE EXPRESSIONS FOR HETEROGENOUS ISOTOPIC EXCHANGE
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摘要: <正> 前文已经导出粒度不均一交换剂的同位素交换反应动力学的速度方程。当粒内扩散和液膜扩散联合控制反应速度时,第i种半径的交换剂上的交换度Abstract: For comparison with results obtained with uniform systems, further numerical calculations are performed for several important frequency distributions of the particle radii. From these numerical calculations, it can be concluded that the ratio of standard deviation and mean radius must not be more than 0.1 so as to avoid an error resulting from calculations with this expression for uniform systems.