DTPA与铀、镎、钚的配位作用Ⅱ.DTPA存在时TBP萃取Np(Ⅳ)的动力学研究

    • 摘要: 研究了DTPA存在时TBP萃取Np(Ⅳ)动力学。研究结果表明,在镎的萃取、反萃过程中HDBP的存在使反应速率变慢;但当体系中含有常量铀时,铀与HDBP结合,提高了镎的萃取和反萃速率

       

      Abstract: COMPLEX REACTIONS OF DTPA WITH URANIUM,NEPTUNIUM AND PLUTONIUM ⅡSTUDY ON EXTRACTION KINETICS OF Np(Ⅳ) BY TBPDTPA SYSTEMWu Qiulin(Institute of Nuclear Energy Technology,Tsinghua University,P.O.Box 1021,Beijing 102201)Chen Shuming Li Guanghong(Beijing Institute of Nuclear Engineering,Beijing 100840)ABSTRACTThe kinetics in extraction process of Np(Ⅳ) by TBP in the presence of DTPA is investigated.The results show that the HDBP can lower the reaction rates of extracting and stripping Np(Ⅳ).But in the presence of sufficient uranium the extraction and stripping of Np(Ⅳ) become quick,as HDBP firstly reacts with uranium.So,in the practical application the reaction rates of extraction processes of Np(Ⅳ) by TBP in the presence of DTPA could not be too tow.Key words DTPA Kinetics Complex Neptunium

       

    /

    返回文章
    返回