Abstract:
COMPLEX REACTIONS OF DTPA WITH URANIUM,NEPTUNIUM AND PLUTONIUM ⅡSTUDY ON EXTRACTION KINETICS OF Np(Ⅳ) BY TBPDTPA SYSTEMWu Qiulin(Institute of Nuclear Energy Technology,Tsinghua University,P.O.Box 1021,Beijing 102201)Chen Shuming Li Guanghong(Beijing Institute of Nuclear Engineering,Beijing 100840)ABSTRACTThe kinetics in extraction process of Np(Ⅳ) by TBP in the presence of DTPA is investigated.The results show that the HDBP can lower the reaction rates of extracting and stripping Np(Ⅳ).But in the presence of sufficient uranium the extraction and stripping of Np(Ⅳ) become quick,as HDBP firstly reacts with uranium.So,in the practical application the reaction rates of extraction processes of Np(Ⅳ) by TBP in the presence of DTPA could not be too tow.Key words DTPA Kinetics Complex Neptunium