乙酰二茂铁缩4-苯氨基硫脲与UO_2~(2+)、Hg~(2+)、Ni~(2+)、Zn~(2+)的希夫碱配合物的合成与表征

摘要: 乙酰二茂铁缩４－苯氨基硫脲（Ｃ_（１９）Ｈ_（１９）Ｎ_３ＳＦｅ）与某些金属离子在无水乙醇中反应得到了希夫碱配合物Ｍ·Ｌ·Ｘ_２·ｎＨ_２Ｏ（Ｍ为ＵＯ_２~（２＋）、Ｈｇ~（２＋）、Ｎｉ~（２＋）、Ｚｎ~（２＋）；Ｌ为Ｃ_（１９）Ｈ_（１９）Ｎ_３ＳＦｅ；Ｘ为ＮＯ３－、Ｃｌ－、ＳＯ_４~（２－）；ｎ＝０—６），并对配合物的组成及某些物理化学性质进行了测试和表征。

Abstract: SYNTHESIS AND CHARACTERIZATION COMPLEXES OF MONOACETYLFERROCENE-4-PHENYL THIOSEMICARBAZONE WITH UO_2~(2+),Hg~(2+),Ni~(2+)OR Zn~(2+)IONSFan Yaoting;Ran Chunling(Department of Chemistry,Zhengzhou University,Zhengzhou 450052)Lu Bingling(School of Chemical Engineering,Dalian University of Technolygy,Dalian 116012)Abstract:Complexes have been synthesized with monoacetylferrocene-4-phenyl thiosemicarbazone(L)combining with,Hg~(2+),Ni~(2+)or Zn~(2+)ions,Characterized through elemental analysis,IR spectrum,UV spectrum and~1HNMR spectrum.The thermal stability and molar conductance have been studied.It shows that L coordinates to the metal ion in a Keto form and is a bidentate ligand.Keywords:Monoacetylferrocene 4-phenyl thiosemicarbanone Uranyl Transition metal ions Shiff complex