冠醚在Rb和Re中子活化分析中的应用研究

    • 摘要: 研究了用18-冠-6(18C6)和苯并15-冠-5(B15C5)的硝基苯溶液分别从给定pH范围的苦味酸水溶液或KOH溶液中定量地萃取Rb和Re,同时研究了影响定量萃取的各种因素以及定量反萃的实验条件。用斜率法确定冠醚与金属离子在溶液中生成2:1配合物。冠醚的选择性定量溶剂萃取已较好地应用于中子活化分析岩石中微量Rb和Re。

       

      Abstract: STUDY ON THE APPLICATION OF CROWN ETHER FOR NEUTRON ACTIVATION ANALYSIS OF RUBIDIUM AND RHENIUM IN ROCK SAMPLESWang Xiaolin;Fu Yibei;Liu Yinong;Xiong Zonghua;Hao Fanhua(Insitute of Nuclear physics and Chemistry,China Academy of Engineering Physics,P.O.Box 525(75),Chengdu,610003)Abstract:The extraction behaviour of rubidium and rhenium with 18-crown6-(18C6)and benzo-15-crown-5(B15C5)in nitrobenzene from picric acid or potassium hydroxide solution are studied and methods for separation and determination are developed.The molar ratio of 18C6 to Rb and B15C5 to Re in the extracted species is probably 2:1.Rubidium and rhenium in rock samples are satisfactorily determined by neutron activation method.Keywords:Crown ether Extraction Neutron activation analysis Rubidium Rhenium Rock

       

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