Abstract:
KINETICS ON THE EXTRACTON OF URANIUM(VI)WITH HDEHP AND LIQUID SUKFACTANT MEMBRANES CONTAINING HDEHP AS A MOBILE CARRIERZHOU ZUMING;DU HUIFANG;WANG HAIFANG;LUO JI(Department of modern Physics,Fudan University,Shanghai, 200433)ABSTRACT The kinetics of extraction of uranium(VI)from sulfuric acid solutions with HDEHP in cyclohexane and liquid surfactant membranes containing HDEHP as a mobile carrier is investigat-ed using Lewis cell technique. By analyzing the effects of stirring speed,temperature and the com-ponent of aqueous phase,organic phase or membrane phase on the rates of extraction of uranium(VI),the rate equations are obtained.The mechanisms of extraction for two processes are dis-cussed.The studies show that the solven extraction is diffusion-controlled and the liquid mem-brane extraction is chemical reaction-controlled.Key words Uranium Extraction Kinetics Di-(2-ethylhexyl) phosphoric acid Liquid membrane.