电位滴定法研究巩县风化煤黄腐酸的解离与配位作用

    • 摘要: 用电位滴定法研究了河南巩县风化煤黄腐酸的解离和配位作用。重点研究了用于维持离子强度的中性盐的浓度及黄腐酸上功能基非均一性对表现解离常数的影响。测定了该黄腐酸分别与Cu(Ⅱ)、La(Ⅲ)、Th(Ⅳ)共存条件下的滴定曲线,研究了不同元素的配位作用的差别。

       

      Abstract: A STUDY ON DISSOCIATION AND COMPLEXATION OF FUIVIC ACID FROM WEATHERED COAL USING POTENTIOMETRIC TITRATIONDU JINZHOU;GAO HUANXIN;LUAN XINFU;JING QI;TAO ZzLU CHANGQING(Nanjing Institute of Soil Science, Academia Sinica, 210008)ABSTRACT The dissociation and complexation of fulvic acid from weathered coal(Gong Xian) are stud-ied by means of potentiometric titrations.The effects of salt concentration and functional groupheterogeneity on the apparent dissociation constants are characterized.Some characteristics of thebinding of the ions Cu(Ⅱ),Th(Ⅳ)and La(Ⅲ)on this fulvic acid are determined.Key words Fulvic acid Potentiometric titration Dissociation Complexation

       

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