邻苯二酚胺羧酰胺和EDTA双螯合剂联合促排铀酰的研究

    • 摘要: 采用pH电位滴定法研究了在25℃、离子强度为0.1mol/l(KNO_3)条件下,铀酰离子和6种2,3-二羟基-5-甲氧羰基苄基胺羧酰胺螯合剂和乙二胺四乙酸(EDTA)的三元配位反应,用SCOGS2程序计算了所形成的配合物的累积生成常数,比较了混配配合物的稳定性,并通过模拟计算讨论了用双螯合剂联合促排铀酰的可能性。

       

      Abstract: STUDIES ON URANYL DECORPORATION BY MIXTUKES OF 2,3-DIHYDROXY-5-CARBO-METHOXYBENZYL AMINOCARBOXYLIC ACID AMIDE AND EDTAWANG YONGWEI;YAN QINGYU;XIE YUYUAN(Shanghai Institute of Materia Medica, Academia Sinica, 200031)ABSTRACT The ternary complexations of uranyl with six 2.3-dihydroxy-5-carbo-methoxybenzylaminocarboxylic acid amide chelating agents and ethylene diamine tetraacetic acid(EDTA) areinvestigated by potentiometric titration at 25℃ and an ionic strength of 0.1mol/l KNO_3. Compo-sitions and formation constants of the mixed ligand chelates are calculated using SCOGS2 pro-gram. The stabilities of mixed ligand chelates are compared. EDTA is likely to coordinate touranyl in EDDA forrn,Computer simulation shows that the decorporation in high uranyl concen-tration using mixtures of chelating agents may be possible. Kev words pH potentiometric Uranyl Catechol aminocarboxylic acid amide EDTA Synergistic decorporation

       

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