用亚铁氰化钾钛从高放废液中去除铯的研究

    • 摘要: 合成了一种球形亚铁氰化钾钛无机离子交换剂,研究了它对模拟酸性高放废液中铯的离子交换性能。结果表明,该材料具有良好的机械稳定性和水力学性能,对艳的离子交换选择性高。在硝酸盐含量达450g/l的模拟酸性高放废液中,Cs ̄+的静态交换容量为1.0mmol/g(干树脂),动态(柱式流动实验)交换容量为0.81mmol/g(干树脂)。

       

      Abstract: REMOVAL OF Cs FROM HIGH LEVEL RADIOACTIVE LIQUID WASTE WITH POTASSIUM TITANIUM HEXACYANOFERRATEJIANG CHANGYIN;WANG SHIZHU;SONG CHONGLI;SUN YONGXIA;WANG QIUPING;XUSHIPING(Institute of Nuclear Energy Technology,Tsinghua University,P.O.Box 1021 ,Beijing 102201)ABSTRACT Spherical potassium titanium hexacyanoferrate has been synthesized by sol-gel method as aninorganic ion exchanger. Its ion exchange properties for Cs are studied.The experimental resultsshow that this material behaves good mechanical stability,excellent hydrodynamic characteristicin an ion exchange column and very high selectivity for Cs. In a simutated acidic high level ra-dioactive liquid waste(HLLW)solution comtaining 450g/l of various nitrares,the static exchangecapacity for Cs is about 1.0mmol/g,and the dynamic exchange capacity tested in column processis about 0.81mmol/g.Key words Potassium titanium hexacyanoferrate Inorganic ion exchanger HLLW Cs

       

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