冠醚萃取法从高放废液中去除锶Ⅲ.二环己基18冠6-辛醇-2对锶的萃取

    • 摘要: 研究了在硝酸介质中二环已基18冠6-辛醇-[2]对锶的萃取。结果表明,这种萃取体系对锶具有良好的萃取性能。同时还研究了水相硝酸浓度、平衡时间及锶浓度对萃取的影响。该萃取体系具有较快的反应动力学,锶浓度对萃取没有很大的影响。体系具有良好的反萃性能,可用去离子水作为反萃剂。从模拟高放废液中对锶和其它主要阳离子的萃取分离表明,该体系不仅对锶具有很好的萃取性能,而且对其它阳离子也具有很好的分离性能。

       

      Abstract: EXTRACTION OF STRONIUM FROM HIGH-LEVEL ACTIVE WASTE WITH CROWN-ETHER Ⅲ.EXTRACTION OF STRONIUM WITH DICYCLOHEXYL-18-CROWN-6-OCTANOL-2HE LONGHAI;WENG XIMEI;YANG DAZHU;SONG CHONGLI(Institute of Nuclear Energy and Technology,TsingHua uniuersity, Beijing,102201)ABSTRACT The extraction of stronium by dicyclohexyl-18-crown-6-octanol-2 from nitric acid so-lutions is investigated.The effluences of the nitric acid,equilibrium time and stronium con-centration are studied.The results show that this extraction system has good dynamics,stronium concentration do not affect the distribution of stronium, water is a good strippingagent.The experiment of extraction stronium and another cation ion in.aqueous phase fromsynthetic HAW shows that this extraction system has high distribution of stronium and highseparation coefficient.This crown-ether-2-octanol extraction process can be used in recoveryof stronium from HAW. Key words Dicyclohexyl-18-crown-6-octanol-2 Stronium Extraction

       

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