用电解精炼法回收和纯化铀和钚的研究Ⅰ.铀-锆合金芯块的直接溶解

    • 摘要: 采用直接溶解法,研究了时间、温度、搅拌与否及芯块表面积等参数对铀-锆合金在液态镉中的溶解影响。实验结果表明,在400℃和500℃、搅拌速度约为150r/min时,铀在液态镉中的溶解度分别为0.4g和2.2g;初始0.5h时,铀溶解速度分别为0.32g/cm ̄2·h和0.05g/cm ̄2·h。U-10Zr合金芯块在液态镉中(液态镉与U-10Zr芯块质量比约为7)直接溶解的合适条件为:溶解温度约480℃,搅拌速度约150r/min,溶解时间约4h。

       

      Abstract: STUDIES ON THE RECOVERY AND PURIFICATION OF URANIUM AND PLUTONIUM BY ELECTREFINING Ⅰ.DIRECT DISSOLUTION OF U-10Zr ALLOY IN LIQUID CADMIUMYE YUXING; GAO YUAN (China Institute of Atomic Energy,P.O. Box 275(26),Beijing,102413)ABSTRACT he effects of time,temperature,total surface area of pellets and stirring on the solubilityand dissolution rate of uranium in liquid cadmium are studied.The experimental results show thatat 500℃ or 400℃ with the stirring rate of some 150r/min ,the solubilities of uranium in liquidcadmium are 2.2g and 0.4g,respectively. At the first 30 min,the dissolution rates of U-10Zr al-loy pellets are 0.32g/cm~2·h and 0.05g/cm~2·h,respectively.The suitable dissolution conditionsfor U-10Zr alloy pellets in liquid cadmium(the ratio of the quality of liquid cadmium to that ofthe pellets≈7)are:temperature,about 480℃;stirring rate,about 150r/min,time,4h.Key words U-10Zr alloy Dissolution Solubility Cadmium

       

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