离子交换法测定双氧铀与巩县风化煤黄腐酸络合物的稳定常数

    • 摘要: 在离子强度为0.1mol/kg,pH值分别为4.0及7.2条件下,用离子交换平衡法测定了国内研究及使用较多的河南巩县风化煤黄腐酸与双氧铀的络合物的稳定常数。在稳定常数的求算中,对Ardakani和Stevenson提出的方法作了修改。

       

      Abstract: DETERMINATION OF STABILITY CONSTANTS OF URANYL WITH FULVIC ACID BY ION EXCHANGE METHODDU JINZHOU;TAO ZUYI(Department of Modern Physics,Lanzhou University,730000)LU CHANGOING(Biochemistry Division,Institute of Nanjing Soil Science,Academia Scinica,210008)ABSTRACT The stability constants of uranyl with the fulvic acid from weathered coal are determinedusing Ardakani-Stevenson's ion exchange method at ionic strength 0.1mol/kg and pH=4.0and 7.2.The complexation constants are found to be 1gβ=4.8 and 7.5 while complexationratio being 1:1 and 1:2,1gβ=10.6and 16.5 while complexation ratio being 2:1 and 3:1.Inthe paper,the Ardakani-Stevenson's method has been modified. Key words Fulvic acid Uranyl Complexes Stability constant Ion exchange

       

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