硝酸铀酰与TDD配合物的合成及性质研究

摘要: 在氯仿－甲醇混合溶剂中，合成了Ｎ，Ｎ，Ｎ’Ｎ’－四苯基－３，６－二氧杂辛二酰胺（ＴＤＤ）与硝酸铀酰的固体配合物，其分子式为［ＵＯ＿２（ＮＯ＿３）＿２（ＴＤＤ）］。通过元素分析、红外光谱、热分析、￣１ＨＮＭＲ谱和摩尔电导率对该配合物进行了表征。

Abstract: SYNTHESIS AND CHARACTEIZATION OF THE COMPLEX OF URANYL NITRATE WITH N，N，N’，N’－TETRAPHENYL-3，6-DIOXAOCTANEDIAMIDELIU WEISHENG; TAN MINYU（Department of Chemistry，Lanzhou University，730000）TAN GANZU（Lanzhou Institute of Chemica Physics，Academia Sinica，730000）ABSTRACT The solid complex of uranyl nitrate with N，N，N’，N’-tetraphenyl-3，6-dioxaoctanediamide（TDD）is prepared in a chloroform-ethanol solution. The new complex with the formula［UO_2（NO_3）_2（TDD）］is characterized by element analysis，IR spectra ，TG-DTA technique，~1HNMR spectra and molar eletric conductivitv.Key wordsN，N，N’，N’-Tetraphenyl-3，6-dioxaoctanediamide Uranyl nitrate Complex