裂片核素在岩石中的迁移研究Ⅵ.~(137)Cs在花岗岩中渗透迁移及吸附动力学
MIGRATION STUDIES OF FISSON PRODUCT NUCLIDES IN ROCKS Ⅵ.THE PERMEABILITY AND THE KINETICS OF ADSORPTION FOR ~(137) Cs IN GRANITE
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摘要: 用动态模型方程描述了裂片核素137Cs(实验中用134Cs模拟 )随地下水流在花岗岩中的渗透迁移过程。由渗透曲线拟合求得模型参数———综合扩散 弥散系数和吸附速率常数 ,并在自行设计的水浴恒温槽中 ,进行了134Cs在花岗岩片上的吸附动力学研究。测定不同 pH值和不同温度下的吸附曲线 ,推算出相应条件下的吸附速率常数及不同 pH值时的吸附能。Abstract: The permeability of 137 Cs in granite is studied with 134 Cs as its simulation nuclide and the kinetic curves of adsorption are measured in a specially designed cell at different pH and temperatures. The kinetic constants and activation energy are obtained. The corresponding kinetic equation describing the migration of 137 Cs is suggested. A series of the important parameters of diffusion, permeability and adsorption are determined. The calculated and experimentally observed dates are compared and discussed.