铀同位素离子交换色谱分离过程的研究
STUDIES ON THE ION EXCHANGE CHROMATOGRAPHIC SEPARATION OF URANIUM ISOTOPES
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摘要: 本工作研究了铀同位素的离子交换色谱浓缩过程,讨论和验证了带迁移过程中坪区消失前浓缩区、贫化区同位素浓度分布分别与穿透、反穿透过程中的浓缩区、贫化区同位素浓度分布相同的观点:提出用三角形面积近似计算总富集量,并由此引入了校正塔板高度的概念,给出了铀同位素浓缩过程中主要参数间相互关系的几个公式,并做了实验验证。Abstract: In this paper a process for the chromatographic enrichment of uranium isotopes is studied. A hypothesis is put forward which sets forth that during the process for band displacement chromatography the isotope distribution within the band in the 235U enriched zone and the 235U depleted zone is the same as in the breakthrough and the inverse breakthrough process respectively. A concept about the calibrated plate height is introduced. Several formulas describing the relationship between some main parameters in the process for the chromatographic enrichment of uranium isotopes are derived. The experimental results are in good agreement with the calculated values by these formulas. The calculations in the process for the chromatographic enrichment of uranium isotopes are thus simplified.