邻菲啰啉单氮氧化物与硝酸钍形成固态配合物的研究
INVESTIGATION OF SOLID COMPLEX OF THORIUM NITRATE WITH 1,10-PHENANTHROLINE-N-OXIDE
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摘要: <正> PhenNO与过渡金属离子具有较好的配位作用,其中某些配合物具有荧光。Th(Ⅳ)与PhenNO的配合物虽有报道,但未涉及其荧光、紫外等性质.我们合成出与文献报道组成不同的配合物Th(PhenNO)_2(NO_3)_4·2H_2O,并对其有关性质进行了研究。荧光性质表明,该配合物具有较强的荧光。Abstract: The solid complex of thorium nitrate with 1,10-phenanthroline-N-oxide (PhenNO), having the composition Th(PhenNO)2(NO3)4·2H2O, is prepared in ethanol. The complex is characterized by elemental analyses, IR spectrum, UV spectrum, fluorescence spectrum, TGA-DSC and molar conductance.
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