Abstract:
STUDY ON SYNERGISTIC EXTRACTION OF RARE EARTH ELEMENTS WITH HBTMPTP AND HPMBPKong Wei Li Deqian(Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemistry,the ChineseAcademy of Sciences ,Changchun 130022)Zhang Xiuying Wang Chaomin(Department of Chemistry,He'nan NormalUniversity,Xinxiang 453002)ABSTRACTThe synergistic extraction of rare earth elements from aqueous nitric acid with benzene solutions of bis(2,4,4trimethylpentyl)monothiophosphinic acid (HBTMPTP,HL) and 1phenyl3methyl4benzoylpyrazolone5 (HPMBP,HA) has been studied.The composition of the extracted complex of La(Ⅲ) has been determined to be LaNO3·HL2·A·2HA by slope analysis and IR spectrophotometer analysis.The equilibrium constants have also been calculated.Key words Synergistic extraction Rare earths HBTMPTP HPMBP