锆与H_2MBP生成萃取界面污物的行为研究

    • 摘要: 观察了TBP的降解产物磷酸一丁酯(H_2MBP)与锆在30%TBP-正十二烷/HNO_3体系中产生界面污物的现象;研究了锆浓度、H_2MBP浓度以及硝酸浓度对界面污物生成的影响,并对界面污物固体进行了红外光谱分析和X射线荧光分析。

       

      Abstract: STUDIES ON INTERFACIAL CRUD FORMATION BY Zr AND H_2MBPZhang Chonghai; Lin Cansheng;Wang Xiaoying;Yang Enbo(China Institute of Atomic Energy,P. O. Box 275 (48),Beijing 102413)Abstract:The behavior of H2MBP and Zr in forming interfacial crud is studied.The experiments show that interfacial crud can be formed by H2MBP and Zr in the system of 30%TBP-n-dodecane HNO3. The forming behavior depends on the concentrations of H2MBP,Zr and HNO3.The fil trated residue of the interfacial crud is analyzed using the techniques of IR spectra and X-ray fluo rescence and it shows that the residue is mainly composed of Zr(MBP)2.Keywords: Zirconium H_2MBP Interfacial crud

       

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