钍(Ⅳ)和铀酰离子与水杨醛缩邻氨基苯甲酸配合物的合成与表征

    • 摘要: 合成了硝酸钍、硝酸铀酰分别与水杨醛缩邻氨基苯甲酸(以H2L表示)配合的2种固体配合物,通过元素分析、差热-热重、红外光谱、紫外光谱、摩尔电导分析等手段,确定配合物的组成分别为[Th(HL)(NO3)2]NO3、[UO2(LH)NO3]。并对它们的某些性质进行了研究

       

      Abstract: PREPARATION AND CHARACTERIZATIONOF COORDINATION COMPOUNDS OF THORIUM ()AND URANYL WITH SALICYLIDENE ANTHRANILIC ACIDAuthor Fan YuhuaBi Caifeng (Department of Applied Chemistry,Shandong Institute of Building Materials,Ji'nan 250022) ABSTRACT Two new solid coordination compounds of thorium nitrate and uranyl nitrate with Schiff base salicylidene anthranilic acid (H2L) have been prepared and characterized by elemental analysis,DTATG,IR,UV,molar conductance and Xray diffraction analysis.The compositions of the coordination compounds NO3 and are confirmed.Some properties of the coordination compounds are studied. Key words Thorium nitrateUranyl nitrateSchiff baseCoordination compounds

       

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