钍(Ⅳ)与邻香草醛缩邻苯二胺双希夫碱配合物的合成与表征

    • 摘要: 合成了硝酸钍与双希夫碱邻香草醛缩邻苯二胺的新固体配合物。通过元素分析、红外光谱、紫外光谱、差热-热重及摩尔电导分析等手段,确定配合物的组成为ThL(NO3)4,研究了它的配位方式和某些物理化学性质。

       

      Abstract: SYNTHESISANDCHARACTERIZATIONOFTh(Ⅳ)COMPLEXOFBIS┐SCHIFFBASEFROMo┐VANILLINANDo┐PHENYLENEDIAMINEFanYuhuaBiCaifengBaoMeng(DepartmentofAppliedChemistry,ShandongInstituteofBuildingMaterials,Ji,nan250022)ABSTRACTThenewsolidcomplexofthoriumnitratewithbis-schifbase(L)derivedfromo-vanilieando-phenylenediaminehasbeensynthesizedandcharacterizedbyelementalanalysis,DTA-TG,IR,UVandmolarconductanceanalysis.ThecompositionofthecomplexisconfirmedtobeThL(NO3)4。KeywordsThoriumBis-schifbaseComplexo-Vanilieando-phenylenediamine

       

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