高酸度电解质溶液中硅酸的形态及其聚合动力学研究

    A STUDY ON THE FORMS AND POLYMERIZATION KINETICS OF SILICIC ACIDS IN STRONGLY ACIDIC ELECTROLYTE SOLUTIONS.

    • 摘要: <正> 在核燃料后处理的水法工艺中,通常用萃取法和离子交换法回收铀、钚等放射性元素。为抑制萃取过程中的乳化和界面污物的形成以及离子交换中的树脂中毒,料液必需先经除硅处理。本工作结合实际任务,对高酸度硅含量较低的电解质溶液中硅的形态及其聚合动力学进行了研究。

       

      Abstract: Studies have been made on the forms of silicic acids and their transformations in strongly acidic electrolyte solutions with Si content of 150 mg/1 and l00mg/1 after different heating treatments and the addition of various flocculating agents. The results show that the polymerization of low molecular weight silicic acids are close to a third order reaction, with an apparent kinetics constant which is roughly proportional to the concentration of hydrogen ion. Although the flocculating agents have little effect on the polymerization kinetics behavior of low molecular weight silicic acids, they do increase the polymerization rate of the intermediate molecular weight silicic acids. The polymerization kinetics of silicic acids can reasonably be described by a consecutive reaction.

       

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