老化钯的吸氚速率

    Investigation of Aging Effects on Palladium Tritium Absorption Rate

    • 摘要: 研究了老化5.9a、N0(He)/N0(Pd)=0.199的老化钯和新鲜钯粉在350kPa条件下吸氚压力随时间的变化规律,分析了钯吸氚反应机制以及老化对钯吸氚速率的影响因素。结果表明:新鲜钯吸氚压力在5s内迅速降低,老化钯吸氚压力降低缓慢;新鲜钯在5s内吸氚量达到N(T)/N(Pd)=0.3,而老化钯N(T)/N(Pd)=0.07;新鲜钯吸氚速率在2s内达到最大值0.11/s,6s时吸氚速率迅速下降至0.02/s;老化钯吸氚速率在1s内达到最大值0.02/s,之后吸氚速率缓慢下降;新鲜钯的最大吸氚速率在α+β相区,而老化钯的最大吸氚速率左移至α相区。钯在贮氚老化时氚衰变产生的3He阻碍氚在钯内部的扩散,影响钯的吸氚速率。

       

      Abstract: The pressure of tritium gas as a function of time during it was being absorbed either by 5.9 year aged palladium powder with helium-to-palladium atomic ratio 0.199 or by fresh palladium powder was experimentally measured for initial pressure 350kPa tritium gas. Mechanism of palladium tritium absorption and aging effects on palladium tritium absorption rate were analysed. The results indicate that the tritium absorption pressure of fresh palladium decreases rapidly in 5s and the tritium absorption pressure of 5.9-year-aged Pd of which the atomic ratio to He is 0.199 decreases slowly. The atomic ratio of tritium and palladium of fresh palladium reaches to 0.3 in 5s, and the atomic ratio of tritium and palladium of aged palladium is just 0.07. The tritium absorption rate of fresh palladium maxes out to 0.11/s in 2s, and falls down rapidly to 0.02/s in 6s. The tritium absorption rate of aged palladium reaches to maximum value at 0.02/s in 1s, and then falls down slowly. The tritium absorption rate of fresh palladium maxes out at α+β-phase, and the tritium absorption rate of aged palladium at α-phase. The 3He that emerges from the decay of tritium blocks the diffusion of tritium and influences the tritium absorption rate.

       

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