Abstract:
DETERMINATION OF ~(88)Y IN NEUTRON ACTIVATED ROCKS──APPLICATION OF SIMPLEX OPTIMIZATION IN SPECTROPHOTOMETRIC ANALYSISWANG WUSHANG;CHEN LIYUN(Northwest Institute of Nuclear Technology,P.O.Box 69(17),Xi′an 710024)ABSTRACT A sensitive andselective spectrophotometric method for the determination of chemical recov-ery of ~(88)Y in neutron activated rocks is developed with modified simplex optirnization method.Thespectrophotometric method is based on the reaction between rare earth elements and chlorophos-phonazo Ⅲ in aqueous solution containing Cu, Phen and ethanol.Under the experimental condi-tions,the maximum absorption wavelength is at 680nm,the molar absorptivity is 1.06×10~4m~2/mol.The absorbance is linearly dependent on the concentration of yttrium when the concen-tration is below 0.6mg/l The variation coefficient is 0. 87%。Key words Simplex optimization method Spectrophotometric method Yttrium Chlorophosphonazo Ⅲ