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模拟镎钚溶液的微波浓缩转型

朴昱曦, 文明芬, 陈吉, 王建晨

朴昱曦, 文明芬, 陈吉, 王建晨. 模拟镎钚溶液的微波浓缩转型[J]. 核化学与放射化学, 2012, 34(5): 292-296.
引用本文: 朴昱曦, 文明芬, 陈吉, 王建晨. 模拟镎钚溶液的微波浓缩转型[J]. 核化学与放射化学, 2012, 34(5): 292-296.
PIAO Yu-xi, WEN Ming-fen, CHEN Ji, WANG Jian-chen. Concentration and Coversion of Simulated Np-Pu Solution by Microwave Method[J]. Journal of Nuclear and Radiochemistry, 2012, 34(5): 292-296.
Citation: PIAO Yu-xi, WEN Ming-fen, CHEN Ji, WANG Jian-chen. Concentration and Coversion of Simulated Np-Pu Solution by Microwave Method[J]. Journal of Nuclear and Radiochemistry, 2012, 34(5): 292-296.

模拟镎钚溶液的微波浓缩转型

Concentration and Coversion of Simulated Np-Pu Solution by Microwave Method

  • 摘要: 用Zr模拟镎钚元素与硝酸、草酸等组成溶液,通过比较微波和油浴减压蒸馏两种加热方式,获得了模拟镎钚的反萃液浓缩转型的工艺参数。主要转型方式为高温浓缩溶液后得到的固体再进行煅烧,使模拟镎钚的反萃液转型为氧化物。借助XRD、BET等分析测试方法对氧化物的性能进行了研究。实验结果表明:微波减压蒸馏比油浴减压蒸馏法减少了浓缩时间,馏出的硝酸可循环使用。微波浓缩得到的固体煅烧后的氧化物比表面积大,易于后续固化研究。
    Abstract: The process parameters of simulated solution of NpPu changing into oxides were obtained by two reduced pressure distillation methods, microwave heating method and oilbath method, and the simulated solution contains of HNO3, H2C2O4 and Zr. The oxides was gained by the method that the concentrated solution is dried and ignited. The properties of oxides were investigated by means of Xray diffraction analysis and surface analysis. The results show that the microwave heating reduced pressure distillation method can shorten concentrating time significantly than oilbath heating method, and the distilled nitric acid can be reused. The oxide obtained by microwave process has large surface area, facilitating the subsequent immobilization study more easy.
  • [1] Laidler J J, Bresee J C. The U S Advanced Fuel Cycle Initiative: Development of Separation Technologies[C]∥Proc Int Cnf for Advances for Nuclear Fuel Cycles, Atalante, Nimes, France, 2004.
    [2] 鲍卫民,常宝祥,果泽洪.微波脱硝用于高加浓铀转型的研究[J].原子能科学与技术,1995,29(3):268-272.
    [3] 鲍卫民,张继荣,宋崇立.硝酸镅(稀土)模拟溶液微波脱硝转型[J].原子能科学技术,2000,34(4):322-327.
    [4] 鲍卫民,李利宇,宋崇立.微波脱硝转型工艺[J].现代化工,1998(1):22-24.
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出版历程
  • 收稿日期:  1899-12-31
  • 修回日期:  1899-12-31
  • 刊出日期:  2012-10-19

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