冯孝贵, 袁建华, 何千舸, 王建晨, 陈靖. 放射性分析中本底对表观计数效率的影响[J]. 核化学与放射化学, 2024, 46(3): 240-245. DOI: 10.7538/hhx.2024.46.03.0240
    引用本文: 冯孝贵, 袁建华, 何千舸, 王建晨, 陈靖. 放射性分析中本底对表观计数效率的影响[J]. 核化学与放射化学, 2024, 46(3): 240-245. DOI: 10.7538/hhx.2024.46.03.0240
    FENG Xiao-gui, YUAN Jian-hua, HE Qian-ge, WANG Jian-chen, CHEN Jing. Influence of Background on Apparent Counting Efficiency in Radioactivity Analysis[J]. Journal of Nuclear and Radiochemistry, 2024, 46(3): 240-245. DOI: 10.7538/hhx.2024.46.03.0240
    Citation: FENG Xiao-gui, YUAN Jian-hua, HE Qian-ge, WANG Jian-chen, CHEN Jing. Influence of Background on Apparent Counting Efficiency in Radioactivity Analysis[J]. Journal of Nuclear and Radiochemistry, 2024, 46(3): 240-245. DOI: 10.7538/hhx.2024.46.03.0240

    放射性分析中本底对表观计数效率的影响

    Influence of Background on Apparent Counting Efficiency in Radioactivity Analysis

    • 摘要: 在放射性分析中,尤其对低活度样品,样品本底的影响是必须要考虑的一个因素。分析实践中,常常涉及计数效率和本底(准确说是确定性本底)的概念,但很少提到表观计数效率和随机性本底。本工作在介绍相关概念的基础上,利用Excel“随机数发生器”研究了本底(包括确定性本底和随机性本底)对表观计数效率的影响规律。本底的影响分为两个方面:一个是因本底扣除不准确而引入的系统误差,它使所有表观计数效率向同一方向偏离计数效率;另一个是本底波动导致的偶然误差,它使表观计数效率在一定范围内随机波动。不管是哪一种误差,本底对表观计数效率的影响均将随着样品活度的降低而增大。对高活度样品,可以不用区分表观计数效率和计数效率这两个概念,但对低活度样品必须区别使用。在有高活度标准源时,不推荐使用通过测量大量低活度样品来获取计数效率的低效方法,宜通过测量活度足够高的标准样品(即本底影响可以忽略的样品)来获取计数效率。

       

      Abstract: In radioactivity analysis, counting efficiency(E) and background(to be precise, it should be deterministic background) are usually discussed, but apparent counting efficiency(E') and random background are rarely mentioned. However, the influence of background(including both deterministic background and random background) on apparent counting efficiency must be considered, especially for samples with low radioactivity. The relation between E and E' can be described as the equation E' = E + ΔB/A, where A is the sample radioactivity, and ΔB is the residue background, including two parts: the counting rate of residual deterministic background caused by inaccurate deduction of background and the counting rate of random background that cannot be deducted. In this paper, E' was studied on the following assumptions: E was fixed at 90%; A was changing from 0.1 to 100, with a step of 0.1(relative unit, similarly hereinafter); and ΔB was set to be fixed, or to follow a specific distribution. The simplest continuous distribution(uniform distribution) and the most commonly used continuous distribution(normal distribution) were chosen for this research, and the function “random number generator ” of the software Excel was used to simulate the random variable ΔB. Specifically speaking, the random variable ΔB was assumed to follow ±0.1·U(0,1), ±0.1·U(−0.5,0.5), ±0.1·N(0.5,1), or ±0.1·N(0,1), where U stands for uniform distribution and N for normal distribution. The influence of background on apparent counting efficiencies is divided into two aspects: one is the systematic error introduced by inaccurate background deduction, which makes all apparent counting efficiencies deviate from the counting efficiency in the same direction; the other is the accidental error caused by background fluctuations, which makes apparent counting efficiency fluctuate within a certain range. Regardless of the error type, the influence of background on apparent counting efficiency will increase as the radioactivity of the sample decreases. For samples with high radioactivity, the difference between apparent counting efficiency and counting efficiency is so small that it can be ignored, therefore it is not necessary to distinguish between the two concepts of apparent counting efficiency and counting efficiency; but for samples with low radioactivity, they must be used differently. Unless there is no standard sample with high radioactivity, it is not recommended to use the inefficient method, which is reported in Lin’s paper(ACS Earth Space Chem, 2022, 6(7): 1868-1875), to obtain counting efficiency by measuring a large number of samples with low radioactivity. It is advisable to obtain counting efficiency by measuring standard samples with sufficiently high radioactivity, in which the influence of background can be negligible.

       

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