Synthesis of Et-Ph-BCTABipy and Its Extraction Properties for Pd2+
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Graphical Abstract
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Abstract
In this work, a phenanthroline based tetradentate neutral sulfur-containing ligand, N,N′-diethyl-N,N′-diphenyl-[2,2′-bipyridine]-6,6′-bis(carbothioamide)(Et-Ph-BCTABipy) was synthesized and characterized by 13C NMR and 1H NMR. The effects of phase contact time, concentration of extractant, and initial concentration of HNO3 and Pd2+ in aqueous phase on the extraction performance of Et-Ph-BCTABipy were studied, and the complex composition of Et-Ph-BCTABipy with Pd2+ was determined by molar ratio method. At the same time, the extraction selectivity of Et-Ph-BCTABipy to Pd2+ was also studied in the coexistence system of Ln(Ⅲ) and Pd2+. The results show that Et-Ph-BCTABipy has strong extraction performance and high extraction selectivity for Pd2+ in HNO3 system. During the extraction process, Et-Ph-BCTABipy combines with Pd2+ in a ratio of 1∶2, and its extraction equilibrium coefficient is Kex=3.42×106.
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