Adsorption of Cs<sup>+</sup> on One-Dimensional Prussian Blue/Diatomite

YAO Chu-qing; DAI Yao-dong; LUO Wei; ZHU Zhong-hua; CHAI Fan-chao

doi:10.7538/hhx.2020.YX.2018071

Journal of Nuclear and Radiochemistry > 2020 > 42(2): 121-128. > DOI: 10.7538/hhx.2020.YX.2018071

YAO Chu-qing, DAI Yao-dong, LUO Wei, ZHU Zhong-hua, CHAI Fan-chao. Adsorption of Cs⁺ on One-Dimensional Prussian Blue/Diatomite[J]. Journal of Nuclear and Radiochemistry, 2020, 42(2): 121-128. DOI: 10.7538/hhx.2020.YX.2018071

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Adsorption of Cs⁺ on One-Dimensional Prussian Blue/Diatomite

College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, China

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Abstract

The treatment of ¹³⁷Cs radioactive waste water is of great importance in the application of nuclear energy and nuclear technology. In this work, one-dimensional structure Prussian blue was synthesized by using surfactant as template, and it was loaded on the surface of diatomite to prepare Prussia blue/diatomite composite material. The performance of one-dimensional Prussian blue/diatomite composite adsorbing Cs⁺ was investigated under different temperatures, adsorption time and pH values. The effects of other cations on adsorption were also studied. The results show that the adsorption capacity(from 42.4 mg/L to 61.6 mg/L) of one-dimensional Prussia blue/diatomite increases with temperature(from 293 K to 318 K). The adsorption behavior is consistent with Langmuir isotherm model and pseudo-second order kinetic equation.
- Prussian blue,
- diatomite,
- Cs⁺,
- adsorption

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[1]	Bostick B C, Vairavamurthy M A, Karthikeyan K G, et al. Cesium adsorption on clay minerals: an EXAFS spectroscopic investigation[J]. Environ Sci Technol, 2002, 36(12): 2670.
[2]	Caccin M, Giacobbo F, Besozzi L, et al. Adsorption of uranium, cesium and strontium onto coconut shell activated carbon[J]. J Radioanal Nucl Chem, 2013, 297(1): 9-18.
[3]	Tsuruoka S, Fugetsu B, Khoerunnisa F, et al. Intensive synergetic Cs adsorbent incorporated with polymer spongiform for scalable purification without post filtration[J]. Mater Express, 2013, 3(1): 21-29.
[4]	Samain L, Grandjean F, Long G J, et al. Relationship between the synthesis of Prussian blue pigments, their color, physical properties, and their behavior in paint layers[J]. J Phys Chem C, 2013, 117(19): 9693-9712.
[5]	Fujita H, Sasano H, Miyajima R, et al. Adsorption equilibrium and kinetics of cesium onto insoluble Prussian blue synthesized by an immediate precipitation reaction between Fe³⁺ and [Fe(CN)₆]^4-[J]. Adsorption-Journal of the International Adsorption Society, 2014, 20(7): 905-915.
[6]	Fujita H, Miyajima R, Sakoda A. Limitation of adsorptive penetration of cesium into Prussian blue crystallite[J]. Adsorption-Journal of the International Adsorption Society, 2015, 21(3): 195-204.
[7]	Vaucher S, Li M, Mann S. Synthesis of Prussian blue nanoparticles and nanocrystal superlattices in reverse microemulsions[J]. Angewandte Chemie, 2010, 39(10): 1793-1796.
[8]	Al-Degs Y, Khraisheh M A, Tutunji M F. Sorption of lead ions on diatomite and manganese oxides modified diatomite[J]. Water Research, 2001, 35(15): 3724-3728.
[9]	Khraisheh M A M, Al-Degs Y S, Mcminn W A M. Remediation of wastewater containing heavy metals using raw and modified diatomite[J]. Chem Eng J, 2004, 99(2): 177-184.
[10]	Liu H, Du X L, Gao P, et al. Distinct magnetic properties of one novel type of nanoscale cobalt-iron Prussian blue analogues synthesized in microemulsion[J]. J Magn Magn Mater, 2010, 322(5): 572-577.
[11]	Tian G, Sun S, Song X, et al. Catanionic surfactants assisted synthesis of dilead pentaoxochromate nanorods[J]. Cryst Res Technol, 2010, 43(8): 817-822.
[12]	赵国玺.表面活性剂物理化学[M].北京：北京大学出版社，1984：155-16.
[13]	Wan Y, Zhao D. On the controllable soft-templating approach to mesoporous silicates[J]. Chem Rev, 2007, 107(7): 2821-2860.
[14]	陈和生，孙振亚，邵景昌.八种不同来源二氧化硅的红外光谱特征研究[J].硅酸盐通报，2011，30(4)：934-937.
[15]	Demirbas E, Dizge N, Sulak M T. Adsorption kinetics and equilibrium of copper from aqueous solutions using hazelnut shell activated carbon[J]. Chem Eng J, 2009, 148(2): 480-487.
[16]	Li Y, Yue Q Y, Gao B Y. Adsorption kinetics and desorption of Cu(Ⅱ) and Zn(Ⅱ) from aqueous solution onto humic acid[J]. J Hazard Mater, 2010, 178(1): 455-461.
[17]	Alghouti M A, Khraisheh M A M, Ahmad M N M, et al. Adsorption behaviour of methylene blue onto Jordanian diatomite: a kinetic study[J]. J Hazard Mater, 2009, 165(1-3): 589-598.
[18]	Elkady M F, Ibrahim A M, El-Latif M M A. Assessment of the adsorption kinetics, equilibrium and thermodynamic for the potential removal of reactive red dye using eggshell biocomposite beads[J]. Desalination, 2011, 278(1): 412-423.
[19]	Hu B Y, Fugetsu B, Yu H W, et al. Prussian blue caged in spongiform adsorbents using diatomite and carbon nanotubes for elimination of cesium[J]. J Hazard Mater, 2012, 217-218(6): 85-91.
[20]	Pau P C F, Berg J O, Mcmillan W G. Application of Stokes’ law to ions in aqueous solution[J]. J Phys Chem, 1990, 94(6): 2671-2679.
[21]	Jin W, Toutianoush A, Pyrasch M, et al. Self-assembled films of prussian blue and analogues: structure and morphology, elemental composition, film growth, and nanosieving of ions[J]. J Phys Chem, B, 2003, 107: 12062-12070.

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Adsorption of Cs⁺ on One-Dimensional Prussian Blue/Diatomite