Determination of Total Rare Earth in HLLW by Spectrophotometry
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Graphical Abstract
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Abstract
In this paper, 90Sr and 137Cs were extracted into the organic phase from high level liquid waste(HLLW) by crown ether-calixarene crown ether in suitable acidic conditions. Then, U, Pu, Th, etc. were also extracted into the organic phase by TOPO-cyclohexane. The water phase was colored by chlorophosphonazo mA in suitable conditions in order to obtain the content of RE in HLLW. The extraction conditions of 90Sr and 137Cs by crown ether-calixarene crown ether and that of TOPO-cyclohexane were investigated. The coloring conditions of chlorophosphonazo mA were studied and determined. The results show that 90Sr and 137Cs are extracted into the organic phase from HLLW by crown ether-calixarene crown ether in 4.5 mol/L HNO3, while RE are not extracted. The absorbance is linear with the quality of RE during the 0.10 mg/L at 670 nm. The relative standard deviation of RE in the simulated-HLLW is 2.3% (n=6), and the recovery rate is 89.9%-97.7%, while, the relative standard deviation of RE in real HLLW is 6.3%(n=3) using this method.
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