YU Bo-wen, QIAN Zheng-hua, ZHOU Shun, LI Lin, QIAO Yan-bo, YAN Ya, QUAN Wei. Effect of Temperature on Performance of Radioactive Fluorine-Containing Concentrated Liquid Phosphate Hydrate Ceramics Solidification[J]. Journal of Nuclear and Radiochemistry, 2021, 43(5): 411-417. DOI: 10.7538/hhx.2021.YX.2020113
    Citation: YU Bo-wen, QIAN Zheng-hua, ZHOU Shun, LI Lin, QIAO Yan-bo, YAN Ya, QUAN Wei. Effect of Temperature on Performance of Radioactive Fluorine-Containing Concentrated Liquid Phosphate Hydrate Ceramics Solidification[J]. Journal of Nuclear and Radiochemistry, 2021, 43(5): 411-417. DOI: 10.7538/hhx.2021.YX.2020113

    Effect of Temperature on Performance of Radioactive Fluorine-Containing Concentrated Liquid Phosphate Hydrate Ceramics Solidification

    • In this paper, phosphate hydrated ceramic waste form was prepared by simulating the radioactive fluorine-containing concentrated liquid with KH2PO4, dead burned magnesium oxide, borax and silica fume at 20-1 000 ℃. The phase composition, microstructure, mechanical properties, porosity and element leaching of the solidified body obtained at different temperatures were studied. The results show that with the increase of temperature, the initial structure of the solidified body collapses, the compressive strength decreases and the porosity increases. When the temperature reaches 800 ℃, some new ore phases of Mg7F2(SiO4)3, Mg2SiO4 and Mg3B2O6 are generated. The smooth and dense network frame contribute to an increasing of the compressive strength and a decreasing of the porosity. The generated ceramic mineralization contributes to the increase of element retention capacity, which is considered that it is a physical effect on Cs and a chemical effect on F.
    • loading

    Catalog

      Turn off MathJax
      Article Contents

      /

      DownLoad:  Full-Size Img  PowerPoint
      Return
      Return