High Temperature Crystallization Synthesis Mn2O3@MoS2 on Composite Materials and Their Adsorption Properties for Uranium
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Graphical Abstract
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Abstract
In this work, MoS2 was prepared using a high temperature molten salt electrolysis. In order to improve the adsorption performance of MoS2 for U(Ⅵ), Mn2O3 was blended on molybdenum disulfide substrate. The laminar structure of MoS2 effectively dispersed the agglomeration of Mn2O3 and introduced uranophilic oxygen group. Scanning electron microscopy, energy dispersive spectroscopy(SEM & EDS), X-ray diffractometer(XRD) and Zeta potentiometers were used for the characterization of Mn2O3@MoS2. The characterization results show that the high temperature crystallization composite has a complete microstructure and stable crystal structure. By controlling the experimental conditions of variables, the adsorption performance of Mn2O3, MoS2 and Mn2O3@MoS2 on U(Ⅵ) in solution was studied. The results indicate that the adsorption performance of Mn2O3@MoS2 is better than those of Mn2O3 and MoS2, and the adsorption equilibrium time is 90 min at pH=5.5. The adsorption kinetics follows the pseudo-2nd-order kinetic model and the adsorption isotherm curve agrees well with the Langmuir model. The maximum single-layer adsorption capacity of Mn2O3@MoS2 is 117.5 mg/g. Increasing of the temperature from 293.15 K to 318.15 K is beneficial for the adsorption progress.
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