Theoretical Studies on Actinides(U and Cm) Endohedral Borospherenes
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Graphical Abstract
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Abstract
The recently discovered all-boron fullerene(D2d B-/040) opened a new chapter in borospherene chemistry. Similar to fullerenes, metal doping is also an important way for modification and functionalization of borospherenes. This work predicts a series of stable actinide metal-doped borospherenes [An@B39]n+ (An=U, n=3; An=Cm, n=2) by using density functional theory. Theoretical calculations show that these borospherenes are all endohedral borospherenes, among which the lowest energy structures of [U@B39]3+ has C3 symmetry, while [Cm@B39]2+ is a C1 structure. Bonding nature analysis shows that delocalized σ and π bonds exist in [U@B39]3+ and [Cm@B39]2+. In addition, the covalent interaction of the U-B bond in [An@B39]n+ is stronger than that of the Cm-B bond. Therefore, the covalency in the An-B bonds may be essential for the formation of these metal-doped borospherenes. This work expands the borospherenes system and provides theoretical clues for the design of novel stable metal endohedral borospherenes.
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