Adsorption Behavior of Sr<sup>2+</sup> on Yangjiang Granite

JIANG Qiao; WANG Yan-hui; CHENG Jian-feng; PAN Yue-long; HONG Tao; BAO Chen-yang; LIU Yu; LENG Yang-chun; WANG Li-tao; TUO Xian-guo

doi:10.7538/hhx.2022.YX.2022001

Journal of Nuclear and Radiochemistry > 2023 > 45(3): 250-258. > DOI: 10.7538/hhx.2022.YX.2022001

JIANG Qiao, WANG Yan-hui, CHENG Jian-feng, PAN Yue-long, HONG Tao, BAO Chen-yang, LIU Yu, LENG Yang-chun, WANG Li-tao, TUO Xian-guo. Adsorption Behavior of Sr²⁺ on Yangjiang Granite[J]. Journal of Nuclear and Radiochemistry, 2023, 45(3): 250-258. DOI: 10.7538/hhx.2022.YX.2022001

Citation:

PDF (914 KB)

Adsorption Behavior of Sr²⁺ on Yangjiang Granite

1.
College of Nuclear Technology and Automation Engineering, Chengdu University of Technology, Chengdu 610059, China
2.
China Nuclear Power Engineering Co., Ltd., Shenzhen 518000, China
3.
School of National Defense Science and Technology, Southwest University of Science and Technology, Mianyang 621000, China

More Information

Graphical Abstract

Abstract

Abstract

Studying the adsorption behavior of Yangjiang granite to Sr²⁺ is very meaningful for the safety assessment of the low- and medium-level nuclear waste repository in Yangjiang. In this study, experimental samples were obtained from the granite rock formations near the low- and medium-level nuclear waste repository in Yangjiang. The static adsorption experiment was performed study the adsorption behavior of Yangjiang surrounding rocks granite on Sr²⁺. And the effect of contact time, initial concentration, reaction temperature, pH, as well as cation and anion on the adsorption behavior of granite was studied in detail. The physical and chemical compositions of Yangjiang granite were investigated by X-ray diffraction spectra(XRD), X-ray fluorescence spectrometer(XRF), scanning electron microscopy-energy dispersive spectroscopy(SEM-EDS), Fourier transform infrared spectra(FTIR) and Zeta potential analyzer. The characterization studies show the granite surface becomes rough after adsorption. The results of static adsorption experiments indicate that adsorption equilibrium time is about 5 days. The Sr²⁺ adsorption decreases with the increase of Sr²⁺ concentration which conforms to the Langmuir isotherm adsorption model and belongs to single-layer adsorption. Under neutral and higher temperature conditions, the adsorption effect is better. The fitting thermodynamic equation suggests that adsorption is a spontaneous endothermic reaction. The ion in groundwater such as Ca²⁺, Mg²⁺, Fe³⁺, NO₃^- all can inhibit the adsorption of Sr²⁺ by Yangjiang granite, while CO₃^2- can interfere with adsorption by forming polymers with Sr²⁺. The results of this study can provide a certain reference for the safety evaluation of the low- and medium-level nuclear waste repository in Yangjiang.
- Sr²⁺,
- Yangjiang granite,
- low- and medium-level nuclear waste repository,
- adsorption behavior

FullText(HTML)

References (38)

References

[1]	Wu M C, Lee C P, Tsai S C, et al. Study on sorption and diffusion of Sr in crushed and intact basalt and granite investigated in through-diffusion experiments[J]. J Radioanal Nucl Chem, 2015, 304(1): 435-441.
[2]	苏琳.Eu(Ⅲ)、Th(Ⅳ)和Se(Ⅳ)在北山花岗岩上的吸附研究[D].兰州：兰州大学,2016.
[3]	Min M, Luo X, Wang J, et al. Sorption behavior of U（Ⅵ）, ²³⁴U（Ⅵ） and ²³⁸U（Ⅵ） onto fracture-filling clays in Beishan granite, Gansu: application to selecting the site of high-level radwaste repository in China[J]. Sci China Earth Sci, 2005, 48(10): 1649-1655.
[4]	谢添，陈超，朱君，等.铀,钚等在某岩土介质上的吸附及其动力学[J].核化学与放射化学，2021,43(4):353-361.
[5]	侯作贤，靳强，叶远虑，等.放射性核素在花岗岩上的吸附行为[J].核化学与放射化学，2015,37(4):207-214.
[6]	陈宗元，张瑞，杨兴龙，等.Co(Ⅱ)和Ni(Ⅱ)在北山花岗岩上的吸附:表面配位模型及线性自由能关系[J].物理化学学报，2013,29(9):2019-2026.
[7]	Jin Q, Su L, Montavon G, et al. Surface complexation modeling of U（Ⅵ） adsorption on granite at ambient/elevated temperature: experimental and XPS study[J]. Chem Geol, 2016, 433: 81-91.
[8]	Tsai S C, Wang T H, Wei Y Y, et al. Kinetics of Cs adsorption/desorption on granite by a pseudo first order reaction model[J]. J Radioanal Nucl Chem, 2008, 275(3): 555-562.
[9]	Wang T H, Li M H, Wei Y Y, et al. Desorption of cesium from granite under various aqueous conditions[J]. Appl Radiat Isot, 2010, 68(12): 2140-2146.
[10]	姜涛，姚军，周舵，等.温度对Np在北山花岗岩上吸附行为的影响[J].核化学与放射化学,2011,33(1):25-31.
[11]	吴涵玉，赵晓岚，王威，等.北山花岗岩与放射性铯相互作用的微观机制研究[J].中国科学:化学，2019,49(1):165-174.
[12]	郭治军，陈宗元，吴王锁，等.Eu(Ⅲ)在北山花岗岩上的吸附作用[J].中国科学：化学，2011,41(5):907-913.
[13]	Lee C P, Lan P L, Jan Y L, et al. Sorption of cesium on granite under aerobic and anaerobic conditions[J]. Radiochim Acta, 2006, 94(9-11): 679-682.
[14]	Jan Y L, Wang T H, Li M H, et al. Adsorption of Se species on crushed granite: a direct linkage with its internal iron-related minerals[J]. Appl Radiat Isot, 2008, 66(1): 14-23.
[15]	贯鸿志，张振涛，苏锡光，等.Am在花岗岩中的吸附行为[J].核化学与放射化学，2009,31(3):189-192.
[16]	Zou Y X, Chen T, Yuan G C, et al. Sorption of iodine on Beishan granite: effect of speciation and humic acid[J]. J Radioanal Nucl Chem, 2018, 317(2): 722-730.
[17]	党海军，侯小琳，刘文元，等.花岗岩介质中Sr,I和Pu的扩散行为[J].核化学与放射化学，2014,36(1):53-59.
[18]	张英杰，于承泽.放射性锶和铯在花岗岩上的吸附与阻滞[J].核科学与工程，1990,10(3):265-272.
[19]	王青海，李晓红，顾义磊，等.锶在砂岩和花岗岩中的分配系数及吸附机制研究[J].矿物岩石，2004,24(2):30-34.
[20]	Qi H, Liu H T, Gao Y. Removal of Sr(Ⅱ) from aqueous solutions using polyacrylamide modified graphene oxide composites[J]. J Mol Liq, 2015, 208: 394-401.
[21]	Xu D H, Zuo R, Han K X, et al. Sorption of Sr in granite under typical colloidal action[J]. J Contam Hydrol, 2020, 233: 103659.
[22]	Li H, He B H, Li P, et al. Adsorption behaviors of Eu(Ⅲ) on granite: batch, electron probe micro-analysis and modeling studies[J]. Environ Earth Sci, 2019, 78(8): 1-9.
[23]	Wang Y H, Jiang Q, Cheng J F, et al. Synthesis and characterization of CTAB-modified bentonite composites for the removal of Cs⁺[J]. J Radioanal Nucl Chem, 2021, 329(1): 451-461.
[24]	He J, Li Y, Su Y, et al. Influence of γ-irradiation and oxygen conditions on the diffusion of I-125 in crushed Beishan granite[J]. Appl Radiat Isot, 2020, 163: 109224.
[25]	冯悦，李兵，廖家莉，等.蛭石和蒙脱石对Sr的吸附性能[J].核化学与放射化学，2009,31(4):230-236.
[26]	姚初清，戴耀东，罗威，等.一维普鲁士蓝/硅藻土复合材料对Cs⁺的吸附[J].核化学与放射化学，2020,42(2):121-128.
[27]	Bao Y Y, Jiang C, Liu Y, et al. Investigation of the adsorption properties of U（Ⅵ） by sulfonic acid-functionalized carbon materials[J]. J Radioanal Nucl Chem, 2021, 330(1): 225-235.
[28]	罗雪梅，丁桑岚，冯启明.膨润土,累托石和沸石对Sr²⁺的吸附性能研究[J].中国非金属矿工业导刊,2009(2):40-42.
[29]	张寒，贺含毅，刘军，等.Eu(Ⅲ)在白云石上的吸附行为[J].核化学与放射化学,2021,43(5):418-425.
[30]	王金明，易发成.沸石对核素Sr²⁺的吸附性能的实验研究[J].中国矿业,2006,15(2):81-84.
[31]	陈廷方，易发成，冯启明，等.北川埃洛石黏土对Sr,Co,Cs的吸附性能研究[J].中国矿业,2011,20(3):74-77.
[32]	余文婷，罗明标，张慧，等.BiCuSO材料吸附放射性废液中的U(Ⅵ)[J].核化学与放射化学,2020,42(1):58-64.
[33]	Wang Z H, Wang Y F, Yao C, et al. Highly efficient removal of uranium（Ⅵ） from aqueous solution using the polyethyleneimine modified magnetic chitosan[J]. J Polym Environ, 2021, 30(3): 855-866.
[34]	Xu Z, Niu Z H, Tang Q F, et al. Adsorption characteristics of Eu(Ⅲ) on colloidal bentonite particles in aqueous solution: impact of colloid concentration, pH, foreign ions, and temperature[J]. J Radioanal Nucl Chem, 2021, 330(3): 765-773.
[35]	Wu H Y, Lin S H, Cheng X, et al. Comparative study of strontium adsorption on muscovite, biotite and phlogopite[J]. J Environ Radioact, 2020, 225: 106446.
[36]	Mishra S P, Tiwari D, Prasad S K, et al. Inorganic particulates in removal of toxic heavy metal ions- part Ⅹ: removal behavior of aluminum hydroxide for Hg(Ⅱ): a radiotracer study[J]. J Radioanal Nucl Chem, 2007, 274(2): 257-263.
[37]	黄力武，黄晖，李兵.天青石矿石中碳酸锶的测定[J].四川化工，2006,5:34-37.
[38]	Jin Q, Wang G, Ge M T, et al. The adsorption of Eu(Ⅲ) and Am(Ⅲ) on Beishan granite: XPS, EPMA, batch and modeling study[J]. Appl Geochem, 2014, 47: 17-24.

[1]	ZHANG Ye, LI Xiang, WANG Wen-tao. Research Progress on Plutonium Adsorption Behavior[J]. Journal of Nuclear and Radiochemistry, 2024, 46(1): 37-45. DOI: 10.7538/hhx.2024.46.01.0037
[2]	ZHOU Lin-sen, JI Ya-qi, SONG Jiang-feng. First-Principle of Adsorption Behavior of H Atom in PuGa Alloy[J]. Journal of Nuclear and Radiochemistry, 2023, 45(2): 153-159. DOI: 10.7538/hhx.2023.45.02.0153
[3]	FAN Lei, WANG Wen-tao, ZHANG Ye, LIU Yue-kun. Adsorption Behavior of Sr2+ on Solid Phase Adsorption Material DMDODGA/P120[J]. Journal of Nuclear and Radiochemistry, 2022, 44(3): 366-376. DOI: 10.7538/hhx.2022.YX.2021044
[4]	HOU Zuo-xian, JIN Qiang, YE Yuan-lu, SHI Ke-liang, GUO Zhi-jun, WU Wang-suo. Adsorption Behavior of Radionuclides on Granite[J]. Journal of Nuclear and Radiochemistry, 2015, 37(4): 207-214. DOI: 10.7538/hhx.2015.37.04.0207
[5]	DENG Xiao-ying, TUO Xian-guo, LENG Yang-chun. Effect of Different Ions on Adsorption of ²³⁹Pu Onto Gaomiaozi Bentonites[J]. Journal of Nuclear and Radiochemistry, 2015, 37(3): 189-192. DOI: 10.7538/hhx.2015.37.03.0189
[6]	ZHOU Duo, LONG Hao-qi, CHEN Xi, WANG Bo, BAO Liang-jin, SONG Zhi-xin, JIANG Tao. Effect of Temperature on Sorption Behavior of Am(Ⅲ) on Granite Under Low-Level-Oxygen-Atmosphere[J]. Journal of Nuclear and Radiochemistry, 2014, 36(4): 216-221. DOI: 10.7538/hhx.2014.36.04.0216
[7]	SONG Feng-li, LI Hui-bo, SU Zhe, CONG Hai-feng, ZHANG Min, LIU Zhi-hui, LIN Can-sheng, WANG Xiao-rong, YE Guo-an. Adsorption Behavior of Cesium on Zirconyl Pyrophosphate[J]. Journal of Nuclear and Radiochemistry, 2014, 36(1): 60-64. DOI: 10.7538/hhx.2014.36.01.0060
[8]	DANG Hai-jun, HOU Xiao-lin, LIU Wen-yuan, LIU Chong, XU Jiang. Diffusivity of Sr, I and Pu in Granite With Through-Diffusion Experiment[J]. Journal of Nuclear and Radiochemistry, 2014, 36(1): 53-59. DOI: 10.7538/hhx.2014.36.01.0053
[9]	FENG Yue, LI Bing, LIAO Jia-li, ZHANG Dong, ZHAO Jun, WU Jiao-jiao, WEN Wei, YANG Yuan-you, LIU Ning. Adsorption of Strontium by Vermiculite and Montmorillonite[J]. Journal of Nuclear and Radiochemistry, 2009, 31(4): 230-236.
[10]	GUAN Hong-zhi, ZHANG Zhen-tao, SU Xi-guang, LONG Hao-qi, WANG Bo, YAO Jun, SONG Zhi-xin, CHEN Xi. Sorption Behavior of Americium on Granite[J]. Journal of Nuclear and Radiochemistry, 2009, 31(3): 189-192.

Cited By

Cited by

Periodical cited type(0)

Other cited types(2)

Get Citation

PDF

XML

Article views (374) PDF downloads (797) Cited by(2)

Turn off MathJax

Article Contents

Abstract

References

Adsorption Behavior of Sr²⁺ on Yangjiang Granite

Abstract

References

Related Articles

Cited by

Periodical cited type(0)

Other cited types(2)

Catalog

Adsorption Behavior of Sr2+ on Yangjiang Granite

Abstract

References

Related Articles

Cited by

Periodical cited type(0)

Other cited types(2)

Catalog

Export File

Citation

Format

Content

Adsorption Behavior of Sr²⁺ on Yangjiang Granite