YANG Jin-ling, ZHANG Sheng-dong, DING You-qian, CUI An-zhi. Radiochemical Procedure for Separation of 93Zr From HLLW[J]. Journal of Nuclear and Radiochemistry, 2010, 32(1): 17-21.
    Citation: YANG Jin-ling, ZHANG Sheng-dong, DING You-qian, CUI An-zhi. Radiochemical Procedure for Separation of 93Zr From HLLW[J]. Journal of Nuclear and Radiochemistry, 2010, 32(1): 17-21.

    Radiochemical Procedure for Separation of 93Zr From HLLW

    • A radiochemical procedure for the separation of 93 Zr based on silica gel separation and TBP extraction was developed. The HLLW solution was first loaded to a silica gel column and was washed with 1 mol/L HNO3 and then desorbed with 10 mol/L HNO3.The eluent was extracted with 100%TBP two times. The kerosene was added into the loaded TBP. The 93Zr was stripped with 0.2mol/L HNO3 twice from TBP-kerosene solution. Subsequently, the 0.2mol/L HNO3 solution was loaded on the second fresh silica gel column and the separation procedures was repeated. The product 93Zr was measured by HPGe γ spectrometer and liquid scintillation analyzer. The results show the highly effective decontamination of the γ-emitting nuclides. The comparison of liquid scintillation spectra between 93Zr and63Ni indicates that the separated 93Zr sample is radiochemical pure. The whole recovery of 93Zr is about 70%.
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