ZHANG Hu, YE Guo-an, LI Li, DENG Wei-qin, LI Hui-rong, LI Gao-liang, YANG Xiao-mei. Preparation 2AF Solution by Electrochemical Method Ⅰ. Electrooxidation of Methyl Hydrazine and N, N Dimethylhydroxylamine[J]. Journal of Nuclear and Radiochemistry, 2010, 32(2): 76-83.
    Citation: ZHANG Hu, YE Guo-an, LI Li, DENG Wei-qin, LI Hui-rong, LI Gao-liang, YANG Xiao-mei. Preparation 2AF Solution by Electrochemical Method Ⅰ. Electrooxidation of Methyl Hydrazine and N, N Dimethylhydroxylamine[J]. Journal of Nuclear and Radiochemistry, 2010, 32(2): 76-83.

    Preparation 2AF Solution by Electrochemical Method Ⅰ. Electrooxidation of Methyl Hydrazine and N, N Dimethylhydroxylamine

    • In order to electrooxidate 1BP to preparate 2AF solution in advanced PUREX process, electrochemical behaviors of methyl hydrazine (MMH) and N, N-dimethylhydroxylamine (DMHAN) were studied by cyclic voltammetry. In addition, electrolytic experiments were carried out with platinum as anode and titanium as cathode at constant current in electrolytic cell without membrane. In nitric acid medium, after MMH is oxidated at anode, DMHAN is indirectly oxidated by nitrous acid at cathode.
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