LIN Mao-sheng, LEI Fu-an, WANG Hang, BAI Jing, DING Hua-jie, WU Xiao-lei, FAN Fang-li, GUO Jun-sheng, QIN Zhi. On-Line Isothermal Gas Chromatography Experiments With NbBr5 and NbOBr3[J]. Journal of Nuclear and Radiochemistry, 2011, 33(2): 65-70.
    Citation: LIN Mao-sheng, LEI Fu-an, WANG Hang, BAI Jing, DING Hua-jie, WU Xiao-lei, FAN Fang-li, GUO Jun-sheng, QIN Zhi. On-Line Isothermal Gas Chromatography Experiments With NbBr5 and NbOBr3[J]. Journal of Nuclear and Radiochemistry, 2011, 33(2): 65-70.

    On-Line Isothermal Gas Chromatography Experiments With NbBr5 and NbOBr3

    • The retention behaviour of volatile bromide and oxybromide of short-lived isotope of niobium in quartz column was studied using on-line isothermal gas chromatography apparatus. The 99Nb nuclide with a half-life of 15 s was produced by spontaneous fission of californium-252. The fission products were continuously and rapidly transported through the capillary to the isothermal chromatography apparatus using the N2/KBr gas-jet techniques. Volatile molecules are formed at the reaction zone kept at 900℃ by adding HBr as reactive gas. Depending on trace amounts of oxygen and water vapour in the system, two species NbBr5 and NbOBr3 are formed. While without oxygen and water vapour, only NbBr5 is formed. After separation, the products were collected by activated charcoal filters and measured synchronously. On the basis of the experimental data and stimulated by the Monte JP2Carlo method, an adsorption enthalpy of (-92±5)kJ/mol for NbBr5 and (-153±5)kJ/mol for NbOBr3 are deduced.
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